Innovative Approach to the Creation of Textile Materials with Antimicrobial Properties

Authors

DOI:

https://doi.org/10.15407/scine17.03.056

Keywords:

environmental responsible, heavy metals, biocides, hygienic properties, thiosulfonates.

Abstract

Introduction. In recent years, there has been a constant search for more advanced and environmentally friendly
means for antimicrobial treatment of cellulose-containing tissues of various intended uses in the textile industry.
Problem Statement. The problem of protection of textile materials and products from microbiological destruction is complex and multifaceted and needs to be solved. Today, one of the methods of protection is to provide textile materials with biocidal properties, which not only prevents the growth of bacteria, but can also ensure a high level of tissue safety. Therefore, we are faced with the task of finding new safe biocidal products.
Purpose. The research has been made to determine the level of safety of textile materials treated by biocidal
substances with the thiosulfonate structure including Ethylthiosulfanilate, Methylthiosulfanilate and Allylthiosulfanilate.
Materials and Methods. The fabrics of different chemical composition were used in the study, designed for the
manufacture of overalls. New preparations of thiosulfonate structure were chosen for impregnation: ethylthiosulfanilate (ETS), methylthiosulfanilate (MTS) and allylthiosulfanilate (ATS). The presence of heavy metals and pesticides was determined by atomic absorption spectrometry with the use of a ZEENIT 650P spectrometer (Germany).
Results. It has been established that the detected level of heavy metals and pesticides in the studied textile materials is insignificant and is within the regulatory requirements. It has been confirmed that the studied biocidal substances are low-toxic and environmentally friendly, because before and after treatment they did not change the hygienic parameters of tissues. A method for imparting biocidal properties to textile materials for the manufacture of overalls, in particular by impregnating textile materials with an alcoholic solution of biocidal products, has been developed. Also due to this treatment, the water absorption of materials decreases by an average of 40%.
Conclusions. The treatment of textile materials with biocidal preparations of the thiosulfonate structure allows
obtaining simultaneously two desired effects for these fabrics: the appropriate bioresistance and water resistance. 

References

Hanczvikkel, A., Vig, A., Toth, A. (2019). Survival capability of healthcare-associated, multidrug-resistant bacteria on untreated and on antimicrobial textiles. Journal of Industrial Textiles, 48(7), 1113—1135. https://doi.org/10.1177/ 1528083718754901

Borkow, G., Gabbay, J. (2008). Biocidal textiles can help fight nosocomial іnfections. Medical Hypotheses, 70(5), 990—994. https://doi.org/10.1016/j.mehy.2007.08.025

Emam, H. E. (2019). Antimicrobial cellulosic textiles based on organic compounds. J. 3 Biotech, 9(1), 29—35. https://doi.org/10.1007/s13205-018-1562-y

Qian, L., Sun, G. (2004). Durable and Regenerable Antimicrobial Textiles: Improving Efficacy and Durability of Biocidal Functions. Journal of Applied Polymer Science, 91(4), 2588—2593. https://doi.org/10.1002/app.13428

Singh, N., Sahu, O. (2019). Sustainable cyclodextrin in textile Applications. The Impact and Prospects of Green Chemistry for Textile Technology. Woodhead Publishing, 83, 83—105. https://doi.org/10.1016/B978-0-08-102491-1.00004-6

Perelshtein, I., Perkas, N., Gedanken, A. (2019). The sonochemical functionalization of textiles. The Impact and Prospects of Green Chemistry for Textile Technology. The Textile Institute Book Series, 161—198. https://doi.org/10.1016/B9780-08-102491-1.00007-1

Lubenets, V., Stadnytska, N., Baranovych, D., Vasylyuk, S., Karpenko, O., Havryliak, V. Novikov, V. (2019). Thiosulfonates: the Prospective Substances against Fungal Infections. IntechOpen, the world’s leading publisher of Open Access books. Fungal Infections, 1—25. http://dx.doi.org/10.5772/intechopen.84436

Nakamura, Y., Matsuo, T., Shimoi, K., Nakamura, Y., Tomita, I. (1993). S-methyl methanethiosulfonate, a new antimutagenic compound isolated from Brassica oleracea L. var. Botrytis. Biological & Pharmaceutical Bulletin, 16(2), 207—209. https://doi.org/10.5772/intechopen.84436

Benkeblia, N., Lanzott, V. (2007). Allium thiosulfinates: Chemistry, biological properties and their potential utilization in food preservation. Food — Global Science Book, 1(2), 193—201.

Lubenets, V. I. (2003). Thiosulphonic acids derivatives: synthesis and properties. Ukrainian Chemistry Journal, 69(3), 109—117 [іn Ukrainian].

Lubenets, V., Luzhetska-Shved, V., Komarovskaya, O., Novikov, V., Kucherenko, L., Smirnov, V., Tolmacheva R. (1999). Antimicrobial Properties of Bioactive Polymers with Thiolsulfonate Fragments. J. Physiologically active substances, 2(28), 101—106 [іn Ukrainian].

Galik, I. S., Semak, B. D. (2014). Problems of formation and evaluation of ecological safety of textiles. Lviv [іn Ukrainian].

Pakholiuk, O. V., Martirosyan, I. A. Lubenets, V. I. (2018). The influence of biocidal treatment of cellulose-containing textile materials on the change of their properties. J. Herald of Khmelnytskyi national university, 6, 94—98 [іn Ukrainian].

Krichevsky, G. E. (2006). Danger and safety of textile products. J Textile industry, 3, 42-45 (2006) [in Russian]

Polishchuk, L. V., Kalashnik, O. V., Kirichenko, O. V. (2016). Investigation of the hygiene and safety indicators of baby textiles. J. Technologies of the food, light and chemical industry, 5(3), 32—38 [in Ukrainian].

Ilić, V., Šaponjić, Z., Vodnik, V., Potkonjak, B., Jovančić, P., Nedeljković, J., Radetić, M. (2009). The influence of silver content on antimicrobial activity and color of cottonfabrics functionalized with Ag nanoparticles. J. Carbohydrate Polymers, 78(3), 564—569.

El-Rafie, M., Ahmed, H. B., Zahran, M. K. (2014). Characterization of nanosilver coated cotton fabrics and evaluation of its antibacterial efficacy. J. Carbohydrate polymers, 107, 174—181.

Emam, H. E., Manian, A. P., Široká, B., Duelli, H., Redl, B. Pipal, A., Bechtold T. (2013). Treatments to impart antimicrobial activity to clothing and householdcellulosic-textiles e why “Nano-silver? J. Clean Prod., 39, 17—23.

Qing, X., Xiating, K., Naiqin, G., Liwen, S., Yanyan, Zh., Feiya, F., Xiangdong, L. (2018). Рreparation of copper nanoparticles coated cotton fabrics with durable antibacterial properties. J. Fibers and Polymers, 19(5), 1004—1013.

Martirosyan, І. А., Pakholiuk, О. V. (2018). Environmental safety of new biocidal productsю. International Multidisciplinary Conference «Science and Technology of the Present Time: Priority Development Directions of Ukraine and Poland» (October 19—20, 2018 Wolomin, Republic of Poland). 1, 69—71 [in Ukrainian].

Martirosyan, I., Pakholiuk, E., Lubenets, V., Peredriy, O. (2018). Investigation on stability of textile materials for overalls processed by new biocidal preparation. Technological Complexes. Scientific journal. 1(15), 52—59.

Martirosyan, I., Pakholiuk, E. (2018). Ecological safety of textile materials for the production of overalls. Materials of the international scientific and practical conference of the applicants of higher education and young scientists “Youth - Science and Production”. Innovative Technologies of Light Industry” (May 17—18, 2018, Kherson), 107—109 [in Ukrainian].

Pylypets, A. Z., Iskra, R. Ya., Havryliak, V. V., Nakonechna, A. V., Novikov, V. P., Lubenets, V. I. (2017). Effects of thiosulfonates on the lipid composition of tissues. Ukr. Biochem. J., 89(6), 56—62.

Lubenets, V. I., Havryliak, V. V., Pylypets, A. Z.. Nakonechna, A. V. (2018). Changes in the spectrum of proteins and phospholipids in tissues of rats exposed to thiosulfanilates. Regulatory mechanisms in biosystems, 9(4), 52—59.

Sungur, Ş, Gülmez, F. (2015). Determination of metal contents of various fibers used in textile industry by MP-AES. Journal of Spectroscopy, 15, 42—48, https://doi.org/10.1155/2015/640271

Qing, X., Yutong, Z., Shenggao, L. (2015). Assessment of heavy metal pollution and human health risk in urban soils of steel industrial city (Anshan), Liaoning, Northeast China. Ecotox. Environ. Safe, 120, 377—385. https://doi.org/10.1016/j. ecoenv.2015.06.019

Kasiri, M. B., Safapour, S. (2014). Natural dyes and antimicrobials for green treatment o textiles. Environ. Chem. Lett., 12(1), 13—18. https://doi.org/10.1007/s10311-013-0426-2

Textile industry poses environmental hazards. URL: http://www.oecotextiles.com/PDF/textile_industry_hazards.pdf (Last accessed: 15.05.2019).

Oeko-tex standard. URL: https://www.oeko- ex.com/ru/consumer/consumers_home/consumer home.xhtml (Last accessed: 15.05.2019).

Perelshtein, I., Perkas, N., Gedanken, A. (2019). The sonochemical functionalization of textiles. The Impact and Prospects of Green Chemistry for Textile Technology, 4, 161—198.

Tuzen, M., Onal, A., Soylak, M. (2008). Determination of trace heavy metals in sone textile products produced in Turkey. Bull. Chem. Soc. Ethiop., 22(3), 379—384.

Cai, J. A., Chen, G., Qiu, J., Jiang, R., Zeng, F., Zhu, F., Ouyang, G. (2016). Hollow fiber based liquid phase microextraction for the determination of organochlorine pesticides in ecological textiles by gas chromatography—mass spectrometry. Talanta, 146, 375—380. https://doi.org/10.1016/j.talanta.2015.08.069

Shvets, V., Karpenko, O., Novikov, V., Lubenets, V. (2017). Antimicrobial Action of Compositions Based on Thiosulfonates and Biosurfactants on Phytopathogens. J.Biotechnology andBiotechnics, 1(1), 109—117. https://doi.org/10.20535/ ibb.2017.1.1.112895

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Published

2021-06-17

How to Cite

Martirosyan, I., Pakholiuk, E., Lubenets , V., Komarovska-Porokhnyavets , O., Monka, N., Nakonechna, A., Peredriy, O. ., & Lutskova, V. (2021). Innovative Approach to the Creation of Textile Materials with Antimicrobial Properties. Science and Innovation, 17(3), 56–66. https://doi.org/10.15407/scine17.03.056

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Section

The Scientific Basis of Innovation